Rihana Terziu, Mihane Dauti,Kledi Xhaxhiu,and Edlira Baraj
This study focuses its attention on the chemical treatment of marble samples in order to create conditions for the protection of cultural heritage objects that consist of these materials. Water penetration, or its vapor condensation in the pores of these material leads to the formation of crystalline ice embryos, which depending on the environmental conditions create internal tensions and disrupt their micro-structure. Their consolidation was carried out by a three stages treatment, starting with 5 % calcium acetate solution for 60 minutes at 200 °C. The second stage occurs after a draining step at 700 °C and for 30 min, and involves the samples treatment with 5 % ammonium sulphate solution. After the application of the same draining procedure as previous, it followed with the third stage which includes the treatment with ammonium oxalate, followed by the same draining procedure. The marble samples were subjects of: 10, 20, 30, 40, and 50 treatments respectively, revealing each time weight increase. Their porosity and specific surface area, assessed by gas porosimetry measurements, continuously decrease at until the last treatment.
1. G.F. Royer-Carfagni. Technical Note On the thermal
degradation of marble.International Journal of
Rock Mechanics and Mining Sciences1999, 36,
119–126.
2. M. Matteini. Conservation of stone monuments
and artifacts: new possibilities off ered by the
ammonium oxalate based treatment. International
Meeting on Science and Technology for Cultural
Heritage2007.
3. Rodríguez-Gordillo J.;Sáez-Pérez M.P. Eff ects of
thermal changes on Macael marble: Experimental
study.Construction and Building Materials
Journal2006 , 6, 355-365.
4. Sudeep M. R;Cathy S. Scotto; C. Jeffrey
Brinker;Development of a surface-specific,
anti-weathering stone preservative treatment.
Advances in architectures series1997, 3, 233-242.
5. Claudia Conti; Chiara Colombo; David Dellasega;
MauroMatteini. Ammonium oxalate treatment:
Evaluation by µ-Raman mapping of the
penetration depth in diff erent plasters. Journal
of Cultural Heritage2011 , 12, 372–379.
6. I. Karatasios; P. Th eoulakis; A. Kalagri; A. Sapalidis;
V. Kilikoglou. Evaluation of consolidation
treatments of marly limestones used in
archaeological monuments. Construction and
Building Materials2009, 23, 2803-2812.
7. Katarina Malaga-Starzec; Jan E. Lindqvist;
BjörnSchouenborg.Experimental study on the
variation in porosity of marble as a function of
temperature.Th e Geological Society 2002, 205,
81-88.
8. Robert C. HCR Handbook of chemistry and
Physics, 59-th Ed; Publisher: CRC Press, Port
Huron, Michigan, United States, 1973, pp 67-187.